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1 Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, UK, 2 Nevis Associates Limited, 34 West Argyle Street, Helensburgh, Dumbartonshire G84 8DD, UK and 3 British Geological Survey, Keyworth, Nottinghamshire NG12 5GG, UK
* E-mail: SJL11{at}esc.cam.ac.uk
(Received 1 December 2003; revised 11 October 2004)
The origin of the regional and stratigraphical variation in the Triassic authigenic clay assemblages of England is discussed in relation to new estimates of the palaeotemperatures experienced by their host sediments and a preliminary study by transmission electron microscopy of their microtextural features. Spore colour index measurements, based on the spore type Deltoidospora s.l. occurring in the sediments (Penarth Group) at the very top of the Triassic sequence, give estimated palaeotemperatures ranging from 6074°C (south Devon) to 8997°C (northeast Yorkshire). Calculated palaeotemperatures, based on a gradient of 25°C/km, for the main one of authigenic clay minerals range from 6377°C to 8997°C for the top to 7185°C to 94104°C for the base. Irregular mixed-layer smectite-chlorite, corrensite and Mg-rich chlorite are associated with calculated palaeotemperatures of 6686°C, 66104°C and 75104°C respectively. The suggestion that elsewhere in the UK corrensite and Mg-rich chlorite were formed at temperatures in excess of 100°C finds no support. Geothermal gradients would have to have been of the order of at least 100300°C/km to obtain these temperatures within the Triassic sediments; such values are associated typically with high-level magmatic intrusions or geothermal systems of which there is no geological evidence. The balance of evidence suggests that the Triassic authigenic clay assemblages formed by neoformation during the early stages of sediment diagenesis under the influence of variation in the alkalinity of the depositional environments.
KEYWORDS: Trias, authigenic, clay assemblage, England, spore colour index, Germanic facies
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