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Clay Minerals; September 2002; v. 37; no. 3; p. 457-463; DOI: 10.1180/0009855023730045
© 2002 Mineralogical Society of Great Britain and Ireland
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Research Paper

The effect of maturation upon the mineralogical and physicochemical properties of illitic-smectitic clays for pelotherapy

C. J. SÁNCHEZ1, J. PARRAS2 and M. I. CARRETERO3,*

1 Laboratorio Mineralogía Aplicada, Facultad de Ciencias Químicas, Universidad de Castilla-La Mancha, 13071 Ciudad Real, 2 Area CC Experimentales, Escuela Universitaria de Magisterio de Ciudad Real-Universidad de Castilla-La Mancha, 13071 Ciudad Real, and 3 Departamento de Cristalografía, Mineralogía y Química Agriícola, Facultad de Química, Universidad de Sevilla, Apdo. 553, 41041 Sevilla, Spain

* E-mail: carre{at}us.es

(Received 9 July 2001; revised 28 December 2001)

Illitic-smectitic clays were matured with a ferruginous, bicarbonate-rich and sulphate-rich water for different periods of time (7, 15, 30, 60 and 90 days), and subjected to discontinuous stirring, to test their use in pelotherapy. A progressive degradation of the clay minerals was observed during the maturation process, with a reduction in the illite and smectite crystallinity, in the percentage of smectites and in the phyllosilicate content. The percentage of <2 µm particles also decreased. These modifications caused changes in the clays’ physicochemical properties, which are evident in an increase in their plasticity index and in slower cooling of the peloid, both of which improved the clays’ effect in pelotherapy.

KEYWORDS: illitic-smectitic clays, physicochemical properties, maturation, pelotherapy







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