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Clay Minerals; April 2000; v. 35; no. 2; p. 375-381
© 2000 Mineralogical Society of Great Britain and Ireland
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Research Paper

Mineralogy of the <2 µm fraction of three mixed-layer clays from southern and central Tunisia

H. BEN RHAIEM1,*, D. TESSIER2 and A. BEN HAJ AMARA1

1 LPM, Faculté des Sciences de Bizerte, 7021 Jarzouna, Tunisia, 2 Station de Recherche du Sol, INRA, 78026 Versailles, France

* E-mail: hafsia.rhaiem{at}fsb.rnu.tn

(Received 31 July 1997; revised 4 August 1999)

Three clay minerals from southern and central Tunisia were characterized. Both XRD quantitative analysis and a chemical method were used to determine the mineralogical and physico-chemical characteristics of the <2 µm clay fractions. The XRD, CEC and specific surface measurement analyses showed that the dominant phase in all samples is illite-smectite with kaolinite and traces of quartz also present. From quantitative XRD, the abundances of the minerals identified are consistent with the measured CEC, specific surface area and TG/DTA properties. Analysis by XRD also showed that the illite-smectite phases are composed of thin stacks (two to a maximum of ten layers per stack) of random illite-smectite and ordered (R1) illite-smectite. There is also some discrete illite.

KEYWORDS: illite-smectite, XRD, CEC, TG/DTA, Tunisia







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