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Clay Minerals; March 2000; v. 35; no. 1; p. 69-76
© 2000 Mineralogical Society of Great Britain and Ireland
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Research Paper

Oil migration makes the difference: regional distribution of carbonate cement {delta}13C in northern North Sea Tertiary sandstones

C. I. MACAULAY1,*,{dagger}, A. E. FALLICK1, R. S. HASZELDINE2 and G. E. McAULAY3

1 Isotope Geosciences Unit, Scottish Universities Research & Reactor Centre, East Kilbride G75 0QF, 2 Department of Geology & Geophysics, Grant Institute, University of Edinburgh, Edinburgh EH9 3JW, and 3 Department of Geology & Applied Geology, University of Glasgow, Glasgow G12 8QQ, UK

* E-mail: calum.macaulay{at}glg.ed.ac.uk

(Received 29 April 1998; revised 11 February 1999)

Carbonate cements in Tertiary reservoir sandstones from the northern North Sea have distinctive carbon isotopic compositions ({delta}13C). Oil migration up faults from deeper structures and biodegradation of oil pools are factors of particular importance in influencing the {delta}13C of carbonate cements in these sandstones. As a result, {delta}13C can be used as an exploration guide to locating the positions of vertical leakoff points from the Jurassic source rocks. The histogram distribution of {delta}13C in these carbonate cements is trimodal, with peaks at around –26, –3 and +12{per thousand} (ranges –22 to –30, +2 to –10 and +8 to +18{per thousand}, respectively). Bacterial processes played major roles in determining this distribution, with oxidative biodegradation of oil resulting in carbonate cements with very negative compositions and bacterial fermentation resulting in the positive {delta}13C cements. {delta}13C distribution patterns may be used to differentiate Tertiary reservoir sandstones from Jurassic in the northern North Sea, and these regional carbonate cement {delta}13C datasets allow geologically useful inferences to be drawn from {delta}13C data from new sample locations.

KEYWORDS: carbonate cements, carbon isotopes, oilfields, diagenesis




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